The nitrile functionality can be hydrolyzed by any diluted acid, not just aqueous HCN. With diluted alkali (dil KOH), the hydrolysis reaction proceeds more quickly. It proceeds in two stages: first, the corresponding amide (acetamide) is formed, and then the corresponding carboxylic acid (acetic acid) is formed. The hydrolysis process releases 1 mol equivalent of NH3, and this ammonia will react with the diluted acid to form the acid’s ammonium salt (NH4Cl, for example).
The nitrile functionality can be hydrolyzed by any diluted acid, not just aqueous HCN. With diluted alkali (dil KOH), the hydrolysis reaction proceeds more quickly. It proceeds in two stages: first, the corresponding amide (acetamide) is formed, and then the corresponding carboxylic acid (acetic acid) is formed. The hydrolysis process releases 1 mol equivalent of NH3, and this ammonia will react with the diluted acid to form the acid’s ammonium salt (NH4Cl, for example).