Since alkanes are sp3 hybridized and halogens can only be introduced to molecules by substituting (replacing another group), they undergo free radical substitution reactions with halogens.
Three steps are involved in the mechanism of free radical substitution: initiation, propagation, and termination. Diatomic halogen molecules are first broken up into two free radical species, which can subsequently join the alkane molecules during the propagation stages.
The stability of these free radicals rises as their electronegativity falls down the group. The fluorine free radical releases the greatest energy during the propagation stage and attacks the alkane more easily since it is the least stable and most electronegative. The least reactive of them is iodine, which comes after chlorine and bromine. In actuality, it is not reactive enough to remove a H atom from an alkane.
Option C is the right response since this order makes sense.
Since alkanes are sp3 hybridized and halogens can only be introduced to molecules by substituting (replacing another group), they undergo free radical substitution reactions with halogens.
Three steps are involved in the mechanism of free radical substitution: initiation, propagation, and termination. Diatomic halogen molecules are first broken up into two free radical species, which can subsequently join the alkane molecules during the propagation stages.
The stability of these free radicals rises as their electronegativity falls down the group. The fluorine free radical releases the greatest energy during the propagation stage and attacks the alkane more easily since it is the least stable and most electronegative. The least reactive of them is iodine, which comes after chlorine and bromine. In actuality, it is not reactive enough to remove a H atom from an alkane.
Option C is the right response since this order makes sense.