Of the options provided, primary alcohols have the highest boiling points.
This is the reason:
_First Alcohols_
The general formula for primary alcohols is RCH2OH, where R stands for an alkyl group. One hydroxyl (-OH) group is joined to a primary carbon atom in them.
Point of Boiling
The strength of an alcohol’s intermolecular forces, especially hydrogen bonds, determines its boiling point. The hydroxyl group, which can create several hydrogen bonds with nearby molecules, gives primary alcohols their strong hydrogen bonding properties.
_Comparation_
Let us compare the various alcohol types’ boiling points:
Because of their strong hydrogen bonds, primary alcohols (RCH2OH) have the highest boiling point.
Because of their weaker hydrogen bonds, secondary alcohols (R2CHOH) have a lower boiling point.
Tertiary alcohols (R3COH) have the lowest boiling point because their hydrogen bonds are the weakest.
_For instance_
– Methanol (CH3OH): primary alcohol, 64.7°C
Propan-2-ol: 82.5°C (secondary alcohol) (CH3CH(OH)CH3)
2. Tertiary alcohol, methylpropan-2-ol (CH3)3COH: 82.3°C
As you can see, because of their strong hydrogen bonds, primary alcohols have the highest boiling points.
Thus, primary alcohol is the right response.
Of the options provided, primary alcohols have the highest boiling points.
This is the reason:
_First Alcohols_
The general formula for primary alcohols is RCH2OH, where R stands for an alkyl group. One hydroxyl (-OH) group is joined to a primary carbon atom in them.
Point of Boiling
The strength of an alcohol’s intermolecular forces, especially hydrogen bonds, determines its boiling point. The hydroxyl group, which can create several hydrogen bonds with nearby molecules, gives primary alcohols their strong hydrogen bonding properties.
_Comparation_
Let us compare the various alcohol types’ boiling points:
Because of their strong hydrogen bonds, primary alcohols (RCH2OH) have the highest boiling point.
Because of their weaker hydrogen bonds, secondary alcohols (R2CHOH) have a lower boiling point.
Tertiary alcohols (R3COH) have the lowest boiling point because their hydrogen bonds are the weakest.
_For instance_
– Methanol (CH3OH): primary alcohol, 64.7°C
Propan-2-ol: 82.5°C (secondary alcohol) (CH3CH(OH)CH3)
2. Tertiary alcohol, methylpropan-2-ol (CH3)3COH: 82.3°C
As you can see, because of their strong hydrogen bonds, primary alcohols have the highest boiling points.
Thus, primary alcohol is the right response.